Low temperature plasma treatments of wool modify only the cuticle surface o
f the fibers, improving their surface wettability, dyeability, fiber cohesi
on, and shrink resistance. The shrink-resist properties obtained with plasm
a treatment do not impart a machine-washable finish, which is an important
end-user demand. However, the shrink resistance of air plasma treated wool
is suitably enhanced by a subsequent biopolymer chitosan application. Using
a qualitative colorimetric method, chitosan adsorption is shown to increas
e after treatment with air plasma. SEM observations yield information about
the etching effect and chitosan adsorption. Given that both kinds of treat
ments, air plasma and chitosan, are environmentally acceptable, a new ecolo
gical shrink-proofing process is proposed.