Free charged and neutral Ag-n clusters were produced by a laser vaporizatio
n cluster source and deposited onto SiO2 substrates resulting in cluster fi
lms. These films were characterized by atomic force microscopy, X-ray diffr
action and resistivity measurements to determine film topography, grain siz
es, dimensions of the coherent scattering regions perpendicular to the film
plane, and the mean free path length of the conduction electrons. An Ag fi
lm grown by molecular beam deposition was investigated using the same chara
cterization techniques. The results show that the deposited clusters keep a
t least part of their shape upon impact on the substrate, giving rise to gr
owth patterns and film properties distinctly different from those of conven
tionally grown films. (C) 1999 Elsevier Science S.A. All rights reserved.