A model for the kinetics of chemiluminescence in the Ru(bipy)(3)(2+)/Ru(phen)(3)(2+)-C2O42--Ce-IV system

Authors
Wu, FW He, ZK Luo, QY Zeng, YE
Citation
Fw. Wu et al., A model for the kinetics of chemiluminescence in the Ru(bipy)(3)(2+)/Ru(phen)(3)(2+)-C2O42--Ce-IV system, ACT CHIM S, 57(11), 1999, pp. 1213-1218
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
57
Issue
11
Year of publication
1999
Pages
1213 - 1218
Database
ISI
SICI code
0567-7351(1999)57:11<1213:AMFTKO>2.0.ZU;2-H
Abstract
A model for the kinetics of chemiluminescence in the Ru(bipy)(3)(2+)/Ru(phe n)(3)(2+) - C2O42-- Ce-IV system has been established according to the mech anism of the reactions. It was used not only to describe the kinetics of ch emiluminescence, but also to calculate the rate constants for rise (r) and decay (f) of the time - dependent chemiluminescence profile, the maximal in tensity (I-max) and the time required to reach maximal intensity (t(max)). The maximal intensity and the area under the I - t curve can be used for th e quantitative analysis.