Synthesis, structure and non-linear optical properties of FeHg(SCN)(4) andMnHg(SCN)(4)

Authors
Yan, YX Fang, Q Yu, WT Yuan, DR Tian, YP Williams, ID Cai, ZG
Citation
Yx. Yan et al., Synthesis, structure and non-linear optical properties of FeHg(SCN)(4) andMnHg(SCN)(4), ACT CHIM S, 57(11), 1999, pp. 1257-1261
Citations number
7
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
57
Issue
11
Year of publication
1999
Pages
1257 - 1261
Database
ISI
SICI code
0567-7351(1999)57:11<1257:SSANOP>2.0.ZU;2-I
Abstract
The title compounds FeHg(SCN)(4) and MnHg(SCN)(4) were synthesized and thei r structures were determined by single crystal X-ray diffraction analysis. Irradiated with a 1064 nm Nd: YAG laser beam, the powdered crystals of FeHg (SCN)(4) show a 532 nm second harmonic intensity of 0.6 times that of urea which was taken as standard sample, whereas the powdered crystals of MnHg(S CN)(4) show a second harmonic intensity of 18 times that of urea. The latte r shows a quite promising application value as a useful nonlinear optical m aterials.