A novel carbon-supported vanadium oxide catalyst for NO reduction with NH3at low temperatures

Citation
Zp. Zhu et al., A novel carbon-supported vanadium oxide catalyst for NO reduction with NH3at low temperatures, APP CATAL B, 23(4), 1999, pp. L229-L233
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
Journal title
APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN journal
09263373 → ACNP
Volume
23
Issue
4
Year of publication
1999
Pages
L229 - L233
Database
ISI
SICI code
0926-3373(199912)23:4<L229:ANCVOC>2.0.ZU;2-L
Abstract
A novel activated carbon-supported vanadium oxide catalyst was studied for SCR of NO with NH3 at low temperatures (100-250 degrees C). The effects of reaction temperature, preparation conditions and SO2 on SCR activity were e valuated. The results show that this catalyst has a high catalytic activity for NO-NH3-O-2 reaction at low temperatures. Preoxidation of the calcined catalyst helps improve catalytic activity. V2O5 loading, other than calcina tion temperature, gives a significant influence on the activity. SO2 in the flue gas does not de-activate the catalyst but improves it. A stability te st of more than 260 h shows that the catalyst is highly active and stable i n the presence of SO2. (C) 1999 Elsevier Science B.V. All rights reserved.