Surface etching by ion sputtering, besides producing equilibrium-oriented p
atterns similar to those obtained by molecular beam epitaxy (MBE), can also
be used to pattern the surface along nonequilibrium orientations, thus ext
ending the possibilities of MBE. By tuning the competition between ion eros
ion at grazing angles and diffusion-induced surface reorganization, it is,
for example, possible to pattern a substrate characterized by a square symm
etry with a well-ordered ripple structure running along any desired directi
on. (C) 1999 American Institute of Physics. [S0003-6951(99)03747-X].