Yr. Kevorkyan et al., Influence of cascade micropores on diffusion fluxes of point defects in reactor vessels materials, ATOM ENERGY, 86(5), 1999, pp. 345-357
The main mechanism determining radiation embrittlement of the materials of
reactor vessels are considered to be a change in the cohesive strength of t
he,grain boundaries resulting from the segregation of surface-active impuri
ties (mainly phosphorous), hardening of the material by precipitations of a
second phase, segregation of impurities onto interphase surfaces of the pr
ecipitate-matrix interface and an associated increase in the hardening effe
ct of the radiation precipitations. The materials of reactor vessels are ir
radiated at a temperature of 250-300 degrees C which is insufficiently high
for the thermal activation of diffusion processes. When describing the pro
cess of an accelerated diffusion of copper and phosphorous atoms by irradia
tion, a model has so far normally been used which neglects the cascade mech
anism for generating defects and also the formation and evolution of point
defect complexes, individual studies taking account of the reduction in the
efficiency of generating point defects in cascades due to the formation of
micropores contain certain deficiencies. The present work is devoted tl? d
eveloping and analyzing a satisfactory model of radiation damage which is t
o a considerable extent free of these deficiencies.