Electrochemical synthesis and characterization of soluble C-60 derivative

Citation
N. Zheng et al., Electrochemical synthesis and characterization of soluble C-60 derivative, CHEM J CH U, 20(11), 1999, pp. 1759-1762
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
20
Issue
11
Year of publication
1999
Pages
1759 - 1762
Database
ISI
SICI code
0251-0790(199911)20:11<1759:ESACOS>2.0.ZU;2-L
Abstract
A new C-60 derivative was synthesized by means of electrochemistry, which e xhibits greater water-solubility and remains stable in water and air. And v ery broad white light spectrum from this derivative has been observed. The bright white light emission of the new material results from a perturbation to the normal C-60 molecule due to the Jahn-Teller distortion of symmetry structure and the interaction between C-60 and -OH. And negative charges re lated to electrolysis product have been proved by using of electrophoresis. According to the infrared and Near-infrared spectrum the derivative contai ns hydroxyl groups. And XPS spectrum, C-13 NMR spectrum prove the derivativ e contains eater carbons.