Accurate leaf-mass determination is a critical factor in estimating the mag
nitude of biogenic hydrocarbon (BHC) emissions from green plants. In severa
l past studies that developed BHC emissions estimates for urban areas, a vo
lumetric approach was used to estimate leaf masses of urban trees. Crown vo
lumes were modeled by geometric solids and then multiplied by species-speci
fic leaf-mass constants (experimentally determined leaf mass-to-volume rati
os) to obtain leaf mass, although associated uncertainties were not well ch
aracterized. The purpose of the present study was to examine the precision
and accuracy of a volumetric approach using geometric solids to compare est
imated leaf masses to measured whole-tree leaf masses, and to compare leaf-
mass constants derived from selective sampling within crowns to whole-tree
values. Accordingly, total leaf masses obtained through tree harvest and le
af removal of 21 urban trees were compared to leaf masses calculated using
geometric solids to model the shapes of tree crowns and leaf-mass constants
found in the literature. Leaf masses were also calculated from recently pu
blished allometric equations. Using the experimentally measured total leaf
mass and dimensions of each tree, whole-tree leaf-mass constants were also
calculated. Results from this study suggest that leaf-mass estimates develo
ped for individual trees through a volumetric approach may be within simila
r to 50% of actual values. For the 21 trees in this study, sums of leaf-mas
s estimates were within similar to 20% of the sum of the measured leaf mass
es when the vertical ellipsoid, sphere, or preferred solids were used. Leaf
masses per unit area of crown projection for these urban trees were greate
r than the values of leaf mass per ground surface area reported for eastern
deciduous forests.