A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3())

Authors
COOK SJ COSTELLO JF DAVIES SG KRUK HT
Citation
Sj. Cook et al., A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3()), Journal of the Chemical Society. Perkin transactions. I, (17), 1994, pp. 2369-2372
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
17
Year of publication
1994
Pages
2369 - 2372
Database
ISI
SICI code
0300-922X(1994):17<2369:ANOSOH>2.0.ZU;2-O
Abstract
Treatment of the salt [Fe(CO)(2)(eta(5)-C5H5)(PPh(3))]Br with potassiu m L-mentholate followed by lithium bromide and methyllithium generates , after work-up and crystallisation, homochiral (S)-(+)[Fe(CO)(eta(5)- C5H5)(PPh(3))COCH3] in greater than or equal to 30% yield.