Assessment of the impact of vehicle emissions on the global environment req
uires accurate data concerning nitrous oxide, N2O, emissions. We report her
ein "real-world" N2O emissions from road vehicles in a tunnel In Wuppertal,
Germany, together with "laboratory" emission measurements conducted at the
Ford Motor Company using a chassis dynamometer with a standard driving cyc
le for 22 different cars and trucks. Consistent results were obtained from
both approaches, suggesting that a good approximation of the average emissi
on factor (g of N2O/g of CO2) = (6 + 2) x 10(-5). This corresponds to an em
ission rate of 16-8 mg of N2O/km for vehicles with fuel economies of 12-6 L
/1110 km (20-40 mi/U.S. gal). N2O emissions from vehicles have a global war
ming impact, which is 1-3% of that of the CO2 emissions from vehicles. We e
stimate that the global vehicle fleet emits 0.18 +/- 0.06 Tg of N2O yr(-1)
(0.11 +/- 0.04 Tg of N yr(-1)), which represents 2-6% of the atmospheric gr
owth rate of this species, In addition to N2O, laboratory vehicle emission
measurements of NH3, HONO, and HCN are reported.