As well as the temperature of the workpiece and the duration of a plasma th
ermochemical process, the characteristics of the treatment atmosphere (pres
sure, flow rates, gas composition) have a great influence on the structure
and the quality of the surface layer imparted. The composition of the proce
ssing atmosphere is usually controlled by the input flow rates but the actu
al percentages of the partial pressures are very often different from the r
atio of the flows. A high-performance gas analyser has been used to investi
gate the partial pressures of the atmosphere constituents during plasma nit
riding and nitrocarburising processes.