1,2-cyclopentadienyl diimine-group 13 complexes

Authors
Ong, CM Stephan, DW
Citation
Cm. Ong et Dw. Stephan, 1,2-cyclopentadienyl diimine-group 13 complexes, INORG CHEM, 38(22), 1999, pp. 5189
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
22
Year of publication
1999
Database
ISI
SICI code
0020-1669(19991101)38:22<5189:1D1C>2.0.ZU;2-P
Abstract
The complexes [(1,2-C5H3(C(Ph)NH)(2))]MR2, M = Al, R = Cl (1), Me (3), Et ( 4), CH2Ph (5), Ph (6), M = Ga, R = Cl (2), Me (7), Et (8), CH2Ph (9), Ph (1 0), are readily prepared. X-ray studies of 1-3 suggest a charge separation and thus electrophilic metal centers.