Homoleptic complexes [Ru(L-L)(3)](2+)(L-L= diphosphine, diarsine)

Authors
La Pensee, AA Higgins, SJ Stuart, CA Bickley, JF
Citation
Aa. La Pensee et al., Homoleptic complexes [Ru(L-L)(3)](2+)(L-L= diphosphine, diarsine), INORG CH C, 2(11), 1999, pp. 524-526
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
11
Year of publication
1999
Pages
524 - 526
Database
ISI
SICI code
1387-7003(199911)2:11<524:HC[DD>2.0.ZU;2-U
Abstract
Homoleptic Ru(II)-diphosphine and Ru(II)-diarsine complexes [Ru(L-L)(3)](OT f)(2) (L-L=Me2P(CH2)(n)PMe2; n=1, dmpm; n=2, dmpe) and 1,2-C6H4(AsMe2)(2) ( diars) have been isolated, in which the Ru(II) state is stabilised to an un precedented degree, and the crystal structure of [Ru(diars)(3)]Cl-2 has bee n determined. (C) 1999 Elsevier Science S.A. All rights reserved.