Synthesis and structure of K-2[HMo6(VI)V(V)O-22(NH3CH2COO)(3)]center dot 8H(2)O: a new example of a polyoxomolybdovanadate coordinated by a glycinatoligand

Authors
Cindric, M Strukan, N Devcic, M Kamenar, B
Citation
M. Cindric et al., Synthesis and structure of K-2[HMo6(VI)V(V)O-22(NH3CH2COO)(3)]center dot 8H(2)O: a new example of a polyoxomolybdovanadate coordinated by a glycinatoligand, INORG CH C, 2(11), 1999, pp. 558-560
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
11
Year of publication
1999
Pages
558 - 560
Database
ISI
SICI code
1387-7003(199911)2:11<558:SASOKD>2.0.ZU;2-A
Abstract
A new complex of formula K-2[(HMo6VO22)-V-VI-O-V(NH3CH2COO)(3)] . 8H(2)O ha s been prepared from molybdenum(VI)) oxide and vanadium(V) oxide in aqueous solution by adding glycine and potassium chloride, and its structure deter mined by X-ray structure analysis. The molybdovanadate anion is built up of six MoO6 edge-sharing octahedra connected into a ring centered by a VO4 te trahedron. The MoO6 octahedra are in pairs linked by the bridging glycine-c arboxylato ligands. (C) 1999 Elsevier Science S.A. All rights reserved.