Vapor-liquid equilibrium of ferrocene in methanol or ethanol.

Authors
Kodama, D Tanaka, H Kato, M
Citation
D. Kodama et al., Vapor-liquid equilibrium of ferrocene in methanol or ethanol., J CHEM EN D, 44(6), 1999, pp. 1252-1253
Citations number
3
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
44
Issue
6
Year of publication
1999
Pages
1252 - 1253
Database
ISI
SICI code
0021-9568(199911/12)44:6<1252:VEOFIM>2.0.ZU;2-G
Abstract
The vapor-liquid equilibrium behavior of ferrocene in methanol or ethanol w as measured at atmospheric pressure in the dilute composition range of ferr ocene with a recirculation still. Equilibrium compositions were determined with an ultraviolet spectrometer having an accuracy of +/-0.000 001 mole fr action of ferrocene, The accuracies of temperature and pressure are +/-0.01 K and +/-0.01 kPa, respectively. The volatilities of ferrocene at infinite dilution were determined to be 0.032 and 0.036 in methanol and ethanol, re spectively.