We discuss photonic crystal properties of semiconductor-opal composites and
explore the possibility of using these structures as photonic bandgap (PBG
) materials in the visible and near-infrared region of the spectrum, Integr
ated reflectance in the optical region is used to show that the photonic cr
ystal behavior of InP-opal is enhanced with respect to the bare matrix as a
result of the new refractive index contrast. Order-N band structure and tr
ansfer matrix calculations have proved to be in good agreement with the exp
eriments. In addition, a strong coupling effect has been observed between C
dS photoluminescence and the photonic structure, which leads to a partial i
nhibition of the spontaneous emission.