FT-Raman spectra of cis-bis(thiourea)selenium(II) chloride and bromide

Authors
Alia, JM Edwards, HGM Fernandez, A Garcia-Navarro, FJ Prieto, M
Citation
Jm. Alia et al., FT-Raman spectra of cis-bis(thiourea)selenium(II) chloride and bromide, J MOL STRUC, 510(1-3), 1999, pp. 107-112
Citations number
33
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
510
Issue
1-3
Year of publication
1999
Pages
107 - 112
Database
ISI
SICI code
0022-2860(19991109)510:1-3<107:FSOCCA>2.0.ZU;2-7
Abstract
The FT-Raman spectra of Se(tu)(2)Cl-2 and Se(tu)(2)Br-2 complexes are repor ted for the first time. The important modifications observed in the Raman a ctive modes of thiourea molecules demonstrate a very strong interaction bet ween the Se(II) ion and the sulfur atom of the ligand. As a result of this coordination, and through a "resonance-assisted" mechanism, an intense hydr ogen-bonded network is present in the crystal structure of the complexes wi th notable vibrational effects. (C) 1999 Elsevier Science B.V. All rights r eserved.