THE PH IN GRAPH

Authors
Citation
R. Delevie, THE PH IN GRAPH, Critical reviews in analytical chemistry, 27(1), 1997, pp. 51-76
Citations number
16
Categorie Soggetti
Chemistry Analytical
ISSN journal
10408347
Volume
27
Issue
1
Year of publication
1997
Pages
51 - 76
Database
ISI
SICI code
1040-8347(1997)27:1<51:TPIG>2.0.ZU;2-7
Abstract
We describe stick diagrams, which are simple graphs designed to provid e quick insight into complicated ionic equilibria. Despite their inher ent crudeness, they can be used to obtain numerical solutions to quant itative equilibrium problems. Moreover, they show when those quantitat ive answers are likely to be too approximate. Finally, we discuss how to make activity corrections, and conclude that activity corrections a re often as large or larger than the errors involved in using stick di agrams. Therefore, in the absence of activity corrections, stick diagr ams are usually quite adequate.