We describe stick diagrams, which are simple graphs designed to provid
e quick insight into complicated ionic equilibria. Despite their inher
ent crudeness, they can be used to obtain numerical solutions to quant
itative equilibrium problems. Moreover, they show when those quantitat
ive answers are likely to be too approximate. Finally, we discuss how
to make activity corrections, and conclude that activity corrections a
re often as large or larger than the errors involved in using stick di
agrams. Therefore, in the absence of activity corrections, stick diagr
ams are usually quite adequate.