Inner-shell excited quartet states in Li-like neon have been investigated b
y beam-foil spectroscopy in the XUV domain. The wavelengths of the transiti
ons n = 2-n' = 3 and n = 2-n' = 4 from the states 1s2ln'l' L-4;l = s, p;l'
= s, p, d in Ne vm were obtained using Hartree-Fock calculations and linear
Z-expansions in the Li sequence. The results of these expansions are in go
od agreement with the measured wavelengths. Our high resolving power allows
us to enhance the wavelength accuracy of quartet transitions previously re
ported. In addition, lifetimes of n' = 3 quartet states are measured. Final
ly, an assignment for a transition from the non-autoionizing inner-shell ex
cited doublet state Ne VIII 1s2p(P-3(o))3d D-2(o) is made and a Li-like qua
rtet E2 transition in our spectra is discussed.