Elastic modulus and thermal conductivity of ultradrawn polyethylene

Citation
Cl. Choy et al., Elastic modulus and thermal conductivity of ultradrawn polyethylene, J POL SC PP, 37(23), 1999, pp. 3359-3367
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
ISSN journal
08876266 → ACNP
Volume
37
Issue
23
Year of publication
1999
Pages
3359 - 3367
Database
ISI
SICI code
0887-6266(199912)37:23<3359:EMATCO>2.0.ZU;2-F
Abstract
The axial and transverse Young's modulus and thermal conductivity of gel an d single crystal mat polyethylene with draw ratios lambda = 1-350 have been measured from 160 to 360 K. The axial Young's modulus increases sharply wi th increasing lambda, whereas the transverse modulus shows a slight decreas e. The thermal conductivity exhibits a similar behavior. At lambda = 350, t he axial Young's modulus and thermal conductivity are, respectively, 20% an d three times higher than those of steel. For this ultradrawn material both the magnitude and the temperature dependence of the axial Young's modulus are close to those of polyethylene crystal. The high values of the axial Yo ung's modulus and thermal conductivity arise from the presence of a large p ercentage (similar to 85%) of long needle crystals. (C) 1999 John Wiley & S ons, Inc.