Effect of first-order phase transition on the vibrational properties of RbIn(MoO4)(2)

Authors
Maczka, M
Citation
M. Maczka, Effect of first-order phase transition on the vibrational properties of RbIn(MoO4)(2), J RAMAN SP, 30(11), 1999, pp. 971-980
Citations number
16
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF RAMAN SPECTROSCOPY
ISSN journal
03770486 → ACNP
Volume
30
Issue
11
Year of publication
1999
Pages
971 - 980
Database
ISI
SICI code
0377-0486(199911)30:11<971:EOFPTO>2.0.ZU;2-#
Abstract
Raman and IR studies of a single orthorhombic crystal and of polycrystallin e trigonal RbIn(MoO4)(2) were performed at ambient temperature. The observe d vibrational modes were assigned to the respective motions of atoms in the unit cells, It was shown that the first-order D-3d(3) -> D-2h(16) phase tr ansition leads to very significant changes in the vibrational properties of the crystal studied. Copyright (C) 1999 John Whey & Sons, Ltd.