Thermal behaviour and analytical study of the production of TiSnOx from the mixed 8-hydroxyquinolinates

Citation
Ls. Guinesi et al., Thermal behaviour and analytical study of the production of TiSnOx from the mixed 8-hydroxyquinolinates, J THERM ANA, 56(2), 1999, pp. 525-531
Citations number
9
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
56
Issue
2
Year of publication
1999
Pages
525 - 531
Database
ISI
SICI code
1388-6150(1999)56:2<525:TBAASO>2.0.ZU;2-G
Abstract
Solubility and pH precipitation studies were carried out to obtain the binu clear complex {[TiO(C9H6NO)(2)][Sn(C9H6NO)(2)]} involving 8-hydroxyquinolin e as chelating agent. The compound, the individual mononuclear complexes an d their physical mixture were evaluated by means of techniques such as TG, DTA, elemental analysis, X-ray diffraction, IR spectroscopy. The properties of the original compounds and also the thermoanalytical conditions exerted a great influence on the degree of crystallinity and on the crystalline ph ase of the mixed oxide obtained as final product of the thermal decompositi on.