D. Visser et al., AN INFRARED SPECTROSCOPIC (IR) AND LIGHT-ELEMENT (LI, BE, NA) STUDY OF CORDIERITES FROM THE BAMBLE SECTOR, SOUTH NORWAY, Lithos, 32(1-2), 1994, pp. 95-107
Infrared absorption spectra and light element contents of several natu
ral cordierites across the Arendal amphibolite-granulite facies transi
tion, Bamble Sector, south Norway are presented. The infrared spectra
record H2O (both type-I and type-II) and CO2 as fluid constituents in
the channels, CO and hydrocarbons were not detected. Type-II water and
(Ca + Na + K) are correlated and show a 2:1 molar ratio. The infrared
and light element data indicate a decrease of Na, type-II H2O, CO2 an
d Li with metamorphic grade, while type-I H2O and Be are variable. The
decrease of these volatiles and alkalies and the low total volatile c
ontents of the granulite facies cordierites are best explained by prog
ressive dehydration and decarbonation processes, possibly related to p
artial melting. A progressive change of the X(H2O) = H2O/(H2O + CO2) r
atio in the cordierites across the transition, as suggested by previou
s studies, is not observed. Greenschist to low-amphibolite facies re-e
quilibrated cordierites show a significant increase in either CO2, or
H2O + CO2. Na is introduced at some localities. The retrograde fluid p
hase is calculated to be CO2-rich.