Effect of physical aging on the microstructure and the crystallization of amorphous poly(aryl ether ether ketone ketone) (PEEKK)

Physical aging of poly(aryl ether ether ketone ketone) (PEEKK) has been inv estigated. Heat flow responses were measured after annealing the amorphous samples obtained by quenching the melt into an ice-water bath close to, but below, the glass transition temperature. The extent of aging is related to the supercooling from the glass transition temperature and to the aging ti me. The activation energy of the aging process, which was estimated by a Wi lliams-Watt expression, is similar in magnitude to that obtained for the co ld crystallization for the aged samples. The quenched glass is a metastable glass. The conformation of molecular chains rearranges with physical aging which results in the formation of a denser packing in the amorphous phase. The dense amorphous phase may form an initial nucleus for crystallization. Isothermal cold crystallization of the aged samples was carried out. The A vrami equation was used to determine the kinetic parameters, and the Avrami constant n is about 2. An Arrhenius expression was used to evaluate the ac tivation energy of relaxation upon physical aging and the activation energy of transportation upon isothermal crystallization. The activation energy o f relaxation is similar in magnitude to that of crystallization for aged sa mples. Results obtained are interpreted as kinetic effects associated with the glass formation process.