Intermolecular Re-H center dot center dot center dot H-N and Re-H center dot center dot center dot base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method

Authors
Desmurs, P Kavallieratos, K Yao, WB Crabtree, RH
Citation
P. Desmurs et al., Intermolecular Re-H center dot center dot center dot H-N and Re-H center dot center dot center dot base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method, NEW J CHEM, 23(11), 1999, pp. 1111-1115
Citations number
51
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
11
Year of publication
1999
Pages
1111 - 1115
Database
ISI
SICI code
1144-0546(199911)23:11<1111:IRCDCD>2.0.ZU;2-Q
Abstract
Hydrogen bonding (Re-H ... H-N) is estimated in solution between ReH5(PPh3) (2)L (L = pyridine, 4-picoline, 4-dimethylaminopyridine, and 4-carbomethoxy pyridine), as hydrogen bond acceptor, and indole, as hydrogen bond donor. R e-H base hydrogen bonding between [Re(PPh3)(2)(MeCN)(4)H][BF4](2) as hydrog en bond donor and various amines as hydrogen bond accepters is much weaker. The binding strengths are estimated by UV-VIS spectroscopy.