The platinum catalysed diboration of alkynes using 1,2-B2Cl2(NMe2)(2): formation of 1-azonia-2-borata-5-borole derivatives

Authors
Anderson, KM Lesley, MJG Norman, NC Orpen, AG Starbuck, J
Citation
Km. Anderson et al., The platinum catalysed diboration of alkynes using 1,2-B2Cl2(NMe2)(2): formation of 1-azonia-2-borata-5-borole derivatives, NEW J CHEM, 23(11), 1999, pp. 1053-1055
Citations number
20
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
11
Year of publication
1999
Pages
1053 - 1055
Database
ISI
SICI code
1144-0546(199911)23:11<1053:TPCDOA>2.0.ZU;2-5
Abstract
The platinum catalysed diboration of alkynes using the diborane(4) compound 1,2-B2Cl2(NMe2)(2) affords high yields of cyclic 1-azonia-2-borata-5-borol e compounds, which arise from redistribution of B-Cl and B-NMe2 bonds.