Citation
Sj. Narayanan et al., Core-modified smaragdyrins: First examples of stable meso-substituted expanded corrole, ORG LETT, 1(4), 1999, pp. 587-590
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060
→ ACNP
Volume
1
Issue
4
Year of publication
1999
Pages
587 - 590
Database
ISI
SICI code
1523-7060(19990826)1:4<587:CSFEOS>2.0.ZU;2-0
Abstract
[GRAPHICS]
A synthetic access to the first members of expanded corroles 1 and 2 is ach
ieved through formation of two direct pyrrole-pyrrole links by an oxidative
coupling reaction. Spectroscopic and structural analysis reveal that 1 and
2 are 22II aromatic macrocycles despite the nonplanar structure and proper
ties resemble that of isocorroles rather than 22II sapphyrins.