Highly enantioselective catalytic conjugate additions to cyclohexadienones

Authors
Imbos, R Brilman, MHG Pineschi, M Feringa, BL
Citation
R. Imbos et al., Highly enantioselective catalytic conjugate additions to cyclohexadienones, ORG LETT, 1(4), 1999, pp. 623-625
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
4
Year of publication
1999
Pages
623 - 625
Database
ISI
SICI code
1523-7060(19990826)1:4<623:HECCAT>2.0.ZU;2-4
Abstract
Enantioselective copper phosphoramidite-catalyzed conjugate addition of dia lkylzinc reagents (R2Zn) to several 4,4-disubstituted cyctohexadienones was achieved with dr's up to 99/1 and ee's up to 99%.