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Practical materials are needed to expedite the detection and screening of h
eavy metals. This Letter describes the synthesis of a new phosphorodithioat
e-based ligand 1 that specifically communicates a color change when exposed
to mercuric ion, The origin of this recognition arises through a charge tr
ansfer and solubility change. This ligand now extends a new means to visual
ly screen and spectroscopically quantify mercuric ion.