Citation
A. Arnone et al., Highly enantiospecific oxyfunctionalization of nonactivated hydrocarbon sites by perfluoro-cis-2-n-butyl-3-n-propyloxaziridine, ORG LETT, 1(2), 1999, pp. 281-284
Citations number
66
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060
→ ACNP
Volume
1
Issue
2
Year of publication
1999
Pages
281 - 284
Database
ISI
SICI code
1523-7060(19990729)1:2<281:HEOONH>2.0.ZU;2-4
Abstract
[GRAPHICS]
Nonactivated hydrocarbon sites of enantiopure compounds are oxyfunctionaliz
ed enantiospecifically by perfluoro-cis-2-n-butyl-3-n-propyloxaziridine und
er remarkably mild reaction conditions. The reaction occurs with retention
of configuration at the oxidized stereogenic center, and the enantiospecifi
city is highly independent from both the carbon framework of the substrate
and the presence of functional groups.