2,2,4,4,6,6-Hexabenzylcyclotristannatellurane (Bn2SnTe)(3). Synthesis and structural characterization of an organometallic single-source precursor tophase-pure, polycrystalline SnTe

Authors
Boudjouk, P Remington, MP Grier, DG Triebold, W Jarabek, BR
Citation
P. Boudjouk et al., 2,2,4,4,6,6-Hexabenzylcyclotristannatellurane (Bn2SnTe)(3). Synthesis and structural characterization of an organometallic single-source precursor tophase-pure, polycrystalline SnTe, ORGANOMETAL, 18(22), 1999, pp. 4534-4537
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
22
Year of publication
1999
Pages
4534 - 4537
Database
ISI
SICI code
0276-7333(19991025)18:22<4534:2(SAS>2.0.ZU;2-R
Abstract
The title compound, (Bn2SnTe)(3) Bn = CH2CsH5, was prepared in high yield b y treating Bn2SnCl2 with (NH4)(2)Te. Details of the synthesis and character ization (H-1, C-13, Sn-119, and Te-125 NMR; IR, single-crystal XRD, and ele mental analyses) are presented. (Bn2SnTe)(3) serves as an efficient single- source precursor to phase-pure cubic SnTe under mild conditions.