Transition-metal-substituted arsaalkenes. 7. Coupling of transition metal carbynes with a methylene arsane moiety: Structure of Tp '(CO)(2)W C-As=C(NMe2)(2) [Tp ' = HB(3,5-Me2HC3N2)(3)]

Authors
Weber, L Dembeck, G Boese, R Blaser, D
Citation
L. Weber et al., Transition-metal-substituted arsaalkenes. 7. Coupling of transition metal carbynes with a methylene arsane moiety: Structure of Tp '(CO)(2)W C-As=C(NMe2)(2) [Tp ' = HB(3,5-Me2HC3N2)(3)], ORGANOMETAL, 18(22), 1999, pp. 4603-4607
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
22
Year of publication
1999
Pages
4603 - 4607
Database
ISI
SICI code
0276-7333(19991025)18:22<4603:TA7COT>2.0.ZU;2-V
Abstract
Condensation of Tp'(CO)(2)M=CCl [1a, M = Mo; 1b, W; Tp' = HB(3,5-Me2HC3N2)( 3)] with the arsaalkene Me3SiAs=C(NMe2)(2) afforded the novel arsaalkenyl c arbyne complexes Tp'-(CO)(2)M=C-As=C(NMe2)(2) (2a) (M = Mo) and 2b (M = W). Methylation of 2a and 2b, occurred at the arsenic atom to give the complex es [Tp'(CO)(2)M=CAs(Me)C(NMe2)(2)](SO3CF3) 3a (M = Mo) and 3b (M = W). Comp ounds 2a,b and 3a,b have been characterized by IR and H-1 and C-13 NMR spec troscopy. In addition, the molecular structure of 2b has been determined by a single-crystal X-ray structural analysis.