Citation
T. Kugita et M. Wakasa, Temperature effect on the kinetics for the reaction of stannyl anion with primary butyl bromide, PHOSPHOR SU, 151, 1999, pp. 271-276
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507
→ ACNP
Volume
151
Year of publication
1999
Pages
271 - 276
Database
ISI
SICI code
1042-6507(1999)151:<271:TEOTKF>2.0.ZU;2-9
Abstract
The decay of the tributylstannyl anion in the presence of primary butyl bro
mide were measured with a modified stopped-flow apparatus at low temperatur
es. The investigation for the differences between that decay at 10 degrees
C and -60 degrees C revealed the formation of the stannyl radical as the in
termediate of this reaction.