A comparison is made between two types of solid particles used in electrorh
eological fluids: particles with homogeneous electrical properties versus l
ayered particles with a semi-conducting core surrounded by an outer layer o
f lower conductivity, Rheological measurements of these suspensions under s
teady sheer and d.c. electric field show that the layered particle system p
roduces the same yield stress but with a substantially reduced electric cur
rent. X-ray spectroscopic analysis confirms that these particles have a thi
n layer of SiOx on the outer surface which causes the reduction in conducti
vity. Measurement of the dielectric permittivity followed by analysis using
the Maxwell-Wagner model of polarization indicates that the conductivity o
f the outer laver is about 0.62 times that of the core region.