Reversible molecular adsorption based on multiple-point interaction by shrinkable gels

Citation
T. Oya et al., Reversible molecular adsorption based on multiple-point interaction by shrinkable gels, SCIENCE, 286(5444), 1999, pp. 1543-1545
Citations number
5
Categorie Soggetti
Multidisciplinary,Multidisciplinary,Multidisciplinary
Journal title
SCIENCE
ISSN journal
00368075 → ACNP
Volume
286
Issue
5444
Year of publication
1999
Pages
1543 - 1545
Database
ISI
SICI code
0036-8075(19991119)286:5444<1543:RMABOM>2.0.ZU;2-C
Abstract
A general approach is presented for creating polymer-gels that can recogniz e and capture a target molecule by multiple-point interaction and that can reversibly change their affinity to the target by more than one order of ma gnitude. The polymers consist of majority monomers that make the gel revers ibly swell and shrink and minority monomers that constitute multiple-point adsorption centers for the target molecule, Multiple-point interaction is e xperimentally proven by power Laws found between the affinity and the conce ntration of the adsorbing monomers within the gels.