ENANTIOPURE 1-HYDROXYMETHYL-2-DIMETHYLAMINOMETHYLFERROCENE AS EFFICIENT CATALYST IN THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES

Authors
NICOLOSI G PATTI A MORRONE R PIATTELLI M
Citation
G. Nicolosi et al., ENANTIOPURE 1-HYDROXYMETHYL-2-DIMETHYLAMINOMETHYLFERROCENE AS EFFICIENT CATALYST IN THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES, Tetrahedron : asymmetry, 5(9), 1994, pp. 1639-1642
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
5
Issue
9
Year of publication
1994
Pages
1639 - 1642
Database
ISI
SICI code
0957-4166(1994)5:9<1639:E1AE>2.0.ZU;2-6
Abstract
A ferrocenyl amino alcohol possessing only planar chirality has been e mployed as a catalyst in the enantioselective alkylation of aldehydes with Et(2)Zn. Seven chiral secondary alcohols in 64 similar to 83% e.e . have been prepared.