Immobilization of Rh(PPh3)(3)Cl on phosphinated MCM-41 for catalytic hydrogenation of olefins

Authors
Shyu, SG Cheng, SW Tzou, DL
Citation
Sg. Shyu et al., Immobilization of Rh(PPh3)(3)Cl on phosphinated MCM-41 for catalytic hydrogenation of olefins, CHEM COMMUN, (23), 1999, pp. 2337-2338
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1999
Pages
2337 - 2338
Database
ISI
SICI code
1359-7345(1999):23<2337:IOROPM>2.0.ZU;2-7
Abstract
The complex Rh(PPh3)(3)Cl immobilized on MCM-41 modified with (OEt)(3)Si(CH 2)(3)PPh2 results in a stable hydrogenation catalyst with turnover frequenc y (TOF) three times higher than that of Rh(PPh3)(3)Cl in the hydrogenation of cyclohexene.