Sterically induced transmutations in cobalt amine chemistry

Authors
Geue, RJ Qin, CJ Ralph, SF Sargeson, AM Skelton, BW White, AH Willis, AC
Citation
Rj. Geue et al., Sterically induced transmutations in cobalt amine chemistry, CHEM COMMUN, (23), 1999, pp. 2351-2352
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1999
Pages
2351 - 2352
Database
ISI
SICI code
1359-7345(1999):23<2351:SITICA>2.0.ZU;2-6
Abstract
Steric forces within a hexaaza bicyclic cobalt cage system cause chromophor e expansions which bring about extraordinary transformations in the CoN6 ch emistry, leading to (CoN6)-N-III/II redox potentials close to +0.8 V (vs. S HE) and Co-II hexaamine complexes that are air and substitution stable.