Bi-edge condensation of imido-rhodium clusters leading to novel planar hexametallic structures

Authors
Tejel, C Bordonaba, M Ciriano, MA Lahoz, FJ Oro, LA
Citation
C. Tejel et al., Bi-edge condensation of imido-rhodium clusters leading to novel planar hexametallic structures, CHEM COMMUN, (23), 1999, pp. 2387-2388
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1999
Pages
2387 - 2388
Database
ISI
SICI code
1359-7345(1999):23<2387:BCOICL>2.0.ZU;2-Z
Abstract
Oxidation of [N(PPh3)(2)][Rh-3(mu-NC6H4Me-p)(2)(CO)(6)] with [FeCp2]PF6 giv es the novel hexarhodium compound [{Rh-3(mu-NC6H4Me-p)(2)(CO)(6)}(2)], cont aining three nearly coplanar condensed metallic cycles forming a doubly-spi ked square, by dimersisation of the trinuclear imidocomplex through the for mation of unsupported metal-metal bonds.