Synthesis and studies on the non-isothermal kinetics of thermal decomposition of complex Zn(C9H6O5N2) center dot 2H(2)O

Authors
Shi, F Wang, DQ
Citation
F. Shi et Dq. Wang, Synthesis and studies on the non-isothermal kinetics of thermal decomposition of complex Zn(C9H6O5N2) center dot 2H(2)O, CHIN J ST C, 18(6), 1999, pp. 437-441
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
02545861 → ACNP
Volume
18
Issue
6
Year of publication
1999
Pages
437 - 441
Database
ISI
SICI code
0254-5861(1999)18:6<437:SASOTN>2.0.ZU;2-D
Abstract
The complex Zn(C9H6O5N2) . 2H(2)O was prepared , its, structure was assigne d on the basis of element analysis, IR, moler conductance. And its kinetics of thermal decomposition was studied under non-isothermal condition with T G. The possible equation of non-isothermal kinetics at third step is sugges ted by the Achar method and the coats-Redfern method and the new method, Th e kinetic equation may be expressed: d alpha/dt = Ae(-E/RT)(1 - alpha).