SYNTHESIS OF NOVEL DONOR-ACCEPTOR MANGANESE(I) COMPLEXES OF FERROCENYLACETYLENE - CRYSTAL-STRUCTURE OF [(C-5H-5)FE(C-5H-4) C-EQUIVALENT-TO-CMN(CO)(3)(PH2PCH(ME)CH2PPH2)] WHICH HAS POTENTIAL FOR 2ND-ORDER NONLINEAR OPTICS

Authors
COLBERT MCB EDWARDS AJ LEWIS J LONG NJ PAGE NA PARKER DG RAITHBY PR
Citation
Mcb. Colbert et al., SYNTHESIS OF NOVEL DONOR-ACCEPTOR MANGANESE(I) COMPLEXES OF FERROCENYLACETYLENE - CRYSTAL-STRUCTURE OF [(C-5H-5)FE(C-5H-4) C-EQUIVALENT-TO-CMN(CO)(3)(PH2PCH(ME)CH2PPH2)] WHICH HAS POTENTIAL FOR 2ND-ORDER NONLINEAR OPTICS, Journal of the Chemical Society. Dalton transactions, (17), 1994, pp. 2589-2590
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
17
Year of publication
1994
Pages
2589 - 2590
Database
ISI
SICI code
0300-9246(1994):17<2589:SONDMC>2.0.ZU;2-5
Abstract
Three novel manganese(I) ferrocenylacetylide complexes have been synth esised and characterised and the crystal structure of [(C5H5)Fe(C5H4)C =CMn(CO)3{Ph2PCH(Me)CH2PPh2}] has been determined, in which the incorp oration of a chiral chelating phosphine leads to crystallisation in th e non-centrosymmetric space group P2(1)2(1)2(1).