Hydrothermal synthesis and electrochemistry of a manganese vanadium oxide,gamma-MnV2O5

Authors
Zhang, F Zavalij, P Whittingham, MS
Citation
F. Zhang et al., Hydrothermal synthesis and electrochemistry of a manganese vanadium oxide,gamma-MnV2O5, ELECTROCH C, 1(11), 1999, pp. 564-567
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ELECTROCHEMISTRY COMMUNICATIONS
ISSN journal
13882481 → ACNP
Volume
1
Issue
11
Year of publication
1999
Pages
564 - 567
Database
ISI
SICI code
1388-2481(199911)1:11<564:HSAEOA>2.0.ZU;2-A
Abstract
A new manganese vanadium oxide MnV2O5 has been synthesized using a mild hyd rothermal reaction. MnV2O5 crystallizes in the orthorhombic system, space g roup Pnma, a=9.7585(2) Angstrom, b=3.5825(1) Angstrom, c=11.2653(2) Angstro m. It is isostructural to gamma-LiV2O5. It reacts readily and reversibly wi th lithium, with a stable capacity but with a large polarization. (C) 1999 Elsevier Science S.A. All rights reserved.