fac-Re(bpy)(CO)(3)(COOMe): A model metallocarboxylate complex of rhenium with a bipyridyl ligand

Authors
Gibson, DH Sleadd, BA Vij, A
Citation
Dh. Gibson et al., fac-Re(bpy)(CO)(3)(COOMe): A model metallocarboxylate complex of rhenium with a bipyridyl ligand, J CHEM CRYS, 29(5), 1999, pp. 619-622
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
5
Year of publication
1999
Pages
619 - 622
Database
ISI
SICI code
1074-1542(199905)29:5<619:FAMMCO>2.0.ZU;2-M
Abstract
The title compound, fac-(2,2'-bipyridyl) (carbomethoxy)rhenium tricarbonyl, crystallizes in the monoclinic system, space group P2(1)/c with the follow ing crystal data: a = 8.37551(1), b = 6.6934(1), c = 26.2098(1) Angstrom, V (Angstrom(3)) = 1535.93(3), Z = 4, and beta = 90.0971(2). The metal environ ment is slightly distorted octahedral with a chelating bipyridyl ligand and a facial arrangement of the carbon monoxide ligands.