Osmotic pressure of electrostatically stabilized magnetic liquids

Citation
F. Cousin et V. Cabuil, Osmotic pressure of electrostatically stabilized magnetic liquids, J MOL LIQ, 83(1-3), 1999, pp. 203-215
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR LIQUIDS
ISSN journal
01677322 → ACNP
Volume
83
Issue
1-3
Year of publication
1999
Pages
203 - 215
Database
ISI
SICI code
0167-7322(199912)83:1-3<203:OPOESM>2.0.ZU;2-A
Abstract
Osmotic pressure measurements are performed, either using a membrane-osmome ter, or by the method of osmotic stress, in order to determine the equation of state of acidic and pH 7 magnetic liquids. Both systems are stabilized by electrostatic repulsions and the magnitude of interactions is estimated through the value of the second-virial coefficient. The effect of the ionic strength and of particle size is investigated. It appears that, even for h igh ionic strength, repulsions dominate the sum of interactions. (C) 1999 E lsevier Science B.V. All rights reserved.