HCN synthesis from methane and ammonia: mechanisms of Pt+-mediated C-N coupling

Citation
M. Diefenbach et al., HCN synthesis from methane and ammonia: mechanisms of Pt+-mediated C-N coupling, J AM CHEM S, 121(45), 1999, pp. 10614-10625
Citations number
62
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN journal
00027863 → ACNP
Volume
121
Issue
45
Year of publication
1999
Pages
10614 - 10625
Database
ISI
SICI code
0002-7863(19991117)121:45<10614:HSFMAA>2.0.ZU;2-Q
Abstract
The Pt+-mediated coupling of methane and ammonia has been studied both expe rimentally and computationally. This system serves as a model for the Degus sa process for the industrial production of the valuable feedstock hydrogen cyanide. Mass spectrometric studies demonstrate that C-N bond formation is catalyzed efficiently by Pt+. Details of the experimentally observed react ion channels have been explored computationally using the B3LYP hybrid DFT/ HF functional. In the first reaction step, Pt+ dehydrogenates CH4 to yield PtCH2+; in contrast, dehydrogenation of ammonia by Pt+ is endothermic and d oes not occur experimentally. Starting from PtCH2+ and NH3, C-N bond format ion, which constitutes the crucial step in making HCN from CH4 and NH3, is achieved via two independent pathways. The major pathway is found to be exo thermic by 23 kcal mol(-1) and yields neutral PtH and CH2NH2+. The second p athway involves a dehydrogenation to yield the aminocarbene complex PtC(H)N H2+ (Delta(r)H = -36 kcal mol(-1)); dehydrogenation of PtC(H)NH2+ to PtCNH is exothermic with respect to PtCH2+ + NH3 (Delta(r)H = -8 kcal mol(-1)) b ut hindered by kinetic barriers. A comparison of Pt+ with other transition metal cations (Fe+, Co+, Rh+, W+, Os+, Ir+, and Au+) shows that Pt+ is uniq ue with respect to its ability to activate 1 equiv of CH4 and to mediate C- N bond coupling.