QUANTIFICATION OF MAXIMUM-ENTROPY SPECTRUM RECONSTRUCTIONS

Citation
P. Schmieder et al., QUANTIFICATION OF MAXIMUM-ENTROPY SPECTRUM RECONSTRUCTIONS, Journal of magnetic resonance [1997], 125(2), 1997, pp. 332-339
Citations number
36
Categorie Soggetti
Physics, Atomic, Molecular & Chemical","Biochemical Research Methods
Volume
125
Issue
2
Year of publication
1997
Pages
332 - 339
Database
ISI
SICI code
Abstract
Maximum-entropy spectrum reconstruction derives much of its power from its nonlinearity, This nonlinearity causes difficulties in several co ntexts, however, including computation of multidimensional spectra and quantification of reconstructed spectra, We describe two methods for avoiding these difficulties: a ''Constant-lambda'' algorithm for perfo rming row-wise reconstructions, which uses a fixed weighting of the en tropy and the experimental constraint in the objective function, and i n situ error analysis, for calibrating the nonlinearity, These methods are applied to data from quantitative J-correlation and relaxation ex periments. (C) 1997 Academic Press.