M. Avella et al., RADICAL POLYMERIZATION OF POLY(BUTYL ACRYLATE) IN THE PRESENCE OF POLY(L-LACTIC ACID) .1. SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF BLENDS, Die Angewandte makromolekulare Chemie, 246, 1997, pp. 49-63
Poly(L-lactic acid) is a biocompatible polyester, semicrystalline, the
rmoplastic, with low versatility in mechanical properties. To overcome
this problem, a reactive blending procedure was performed by grafting
an acrylic rubber, n-butyl acrylate, via water suspension polymerizat
ion onto poly(l-lactic acid) dissolved in an organic solvent. It was p
ossible to isolate the copolymeric phase formed from the two polymers
and characterize it by using NMR and DSC techniques. Mechanical tests
on blends gave no satisfactory response, probably because the rubbery
phase is composed essentially of viscous linear macromolecules, not ab
le to perform elastic properties. Work is in progress to modify the sy
nthetic pathway to incorporate diacrylates in order to realize a rubbe
ry phase at least partially cross-linked.