The feasibility of using recycled FR-4 epoxy laminates as reinforcing
fillers in manufacturing unsaturated polyester (UP) composites was stu
died using differential scanning calorimetry (DSC), and flexural tests
. UP resins filled with recycled laminates had a higher flexural stren
gth and modulus than the plain UP because of energy dissipation effect
s from glass fibers and rigid epoxy resins in the laminates. The size
and loading of the laminates affected the flexural properties of the m
olded products. The addition of CaCO3 fillers and Cu decreased the fle
xural strength but promoted the flexural modulus of the UP. As reveale
d by DSC measurements the presence of laminates affected the free-radi
cal reaction of the UP resin and decreased the curing rate. The curing
kinetics were also dependent on the size and relative content of the
laminates added.