Study on transmetalation of a nickelacycle with organometallic reagents

Authors
Sato, Y Takanashi, T Mori, M
Citation
Y. Sato et al., Study on transmetalation of a nickelacycle with organometallic reagents, ORGANOMETAL, 18(24), 1999, pp. 4891-4893
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
24
Year of publication
1999
Pages
4891 - 4893
Database
ISI
SICI code
0276-7333(19991122)18:24<4891:SOTOAN>2.0.ZU;2-B
Abstract
A transmetalation of the oxanickelacycle 7, generated from the 1,3-diene an d tethered aldehyde in 6 via oxidative cycloaddition to a zerovalent nickel complex, with various organometallic reagents was investigated. It was fou nd that the tandem reaction, i.e., cyclization of 6 followed by transmetala tion of the resulting oxanickelacycle 7, proceeded smoothly using a catalyt ic amount of zerovalent nickel complex.